Montelcino is an amazing town too. Did you check out La Fortezza? They were pouring Sassicaia and Ornellaia by the glass, as well as Antinori's Pian delle Vigne BdM. Pretty amazing. The 97's have entered their prime, and the 99's are pretty much there too.

For Italian wine it's hard to beat the Super's, and I'm a big Amarone fan as well.